Yes, throughput doesn't have to be in range [0, 1]. That's a reason why you have to use exposure settings, because for differente accumulation time, brightness of an image might differ. Nathan Reed described it in details here - https://computergraphics.stackexchange.com/a/10244/10129
Your final results and number of fireflies and bright surfaces, depends on PDF that you'll be using. By using Normal Distribution Function PDF, you'll get good results, because NDF is the most determining factor of BRDF shape. Relate to this blog post for details - https://schuttejoe.github.io/post/ggximportancesamplingpart1/
Back to throughput range. Assuming that you're sampling based on NDF, you'll get fireflies in case of having values in specific range, when light source is shining from very low angle and you're looking directly at the object. Therefore, your denominator might be much greater than nominator and result in small PDF causing fireflies:
$$
p_i(w_m, w_o) = \frac{D(w_m)(w_g \cdot w_i)}{4|w_g \cdot w_m|}
$$
Since 2014, Heitz was working on BSDFs, presenting good results in same year by sampling visible normals [2]. In 2017, he published much simpler, faster and better paper, improving his method [3]. There are also 2015 and 2016 papers in related field, but I haven't read them, but it might be beneficial if you're interested in BSDF. I would recommend checking his first 2014's work (1) where he explains physical assumption on which BRDF is based. It's worth knowing, what NDF and Geometry Shadowing exactly means in BRDF.
Also, there is a lot of good reading in pbrt book, especially:
(1) Eric Heitz - Understanding the Masking-Shadowing Functionin Microfacet-Based BRDFs http://jcgt.org/published/0003/02/03/paper.pdf
(2) Eric Heitz, Eugene d’Eon - Importance Sampling Microfacet-Based BSDFs using the Distribution of Visible Normals https://hal.inria.fr/hal-00996995v1/document
(3) Eric Heitz - A Simpler and Exact Sampling Routine for the GGXDistribution of Visible Normals https://hal.archives-ouvertes.fr/hal-01509746/document